Improving Estimates of the Crystallization Driving Force [Elektronisk resurs] Investigation into the Dependence on Temperature and Composition of Activity Coefficients in Solution

• The influence of temperature and composition on solution activity coefficients has been investigated. Under most conditions, the temperature dependence of the activity coefficient is much weaker than the composition dependence. A novel and more accurate approach to estimate crystallization driving forces is proposed, where, rather than neglecting the activity coefficient ratio, it can be estimated from solid−liquid equilibrium data. 

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Indexterm och SAB-rubrik

activity coefficient

thermodynamics

solubility