Effect of incorporating different ZIF-8 crystal sizes in the polymer of intrinsic microporosity, PIM-1, for CO2/CH4 separation [Elektronisk resurs]
-
Yahia, Mohamed (författare)
-
Phan Le, Quynh Nhu (författare)
-
Ismail, Norafiqah (författare)
-
Essalhi, Mohamed (författare)
-
Sundman, Ola (författare)
-
Rahimpour, Ahmad (författare)
-
Dal-Cin, Mauro M. (författare)
-
Tavajohi Hassan Kiadeh, Naser (författare)
-
Umeå universitet Teknisk-naturvetenskapliga fakulteten (utgivare)
- Publicerad: Elsevier, 2020
- Engelska.
-
Ingår i: Microporous and Mesoporous Materials. - 1387-1811.
-
Läs hela texten
-
Läs hela texten
-
Läs hela texten
- Relaterad länk:
-
http://www.umu.se/ (Värdpublikation)
Sammanfattning
Ämnesord
Stäng
- Effective and economical carbon dioxide-methane separation (CO2/CH4) is highly desirable in several industries such as sweetening natural gases and renewable natural gas (RNG) from biogas and landfills. Among the different separation technologies, membrane separation has been shown to have lower cost of production and lower CH4 losses. In this study, Zeolitic Imidazole Frameworks (ZIF-8) crystals with sizes varying from 45 nm to 450 nm were synthesized and incorporated in the polymer of intrinsic microporosity, PIM-1, to form mixed matrix membranes (MMMs). The structure, morphology, and physicochemical properties of the MMMs were characterized by 1H NMR, FTIR, XRD, TGA, and SEM. ZIF-8 crystal size was controlled using the concentration of sodium formate. The influence of the ZIF-8 crystal size on MMMs was studied by sorption, gas permeability, and aging of the membranes. The MMMs with ZIF-8 crystals of 120 nm particle diameter yielded the greatest improvement in gas transport properties; the CO2/CH4 selectivity-CO2 permeability was 11.4 and 9700 Barrer compared to PIM-1 with 6.4 and 9300 Barrer respectively. The former is near the Robeson 2008 upper bound, while PIM-1 is on the 1991 upper bound. After 40 days of aging, selectivity increased and permeability decreased; the changes were parallel to the Robeson upper bounds indicating increased polymer packing and diffusivity selectivity.
Ämnesord
- Engineering and Technology (hsv)
- Chemical Engineering (hsv)
- Other Chemical Engineering (hsv)
- Teknik och teknologier (hsv)
- Kemiteknik (hsv)
- Annan kemiteknik (hsv)
- Engineering and Technology (hsv)
- Chemical Engineering (hsv)
- Chemical Process Engineering (hsv)
- Teknik och teknologier (hsv)
- Kemiteknik (hsv)
- Kemiska processer (hsv)
- Natural Sciences (hsv)
- Chemical Sciences (hsv)
- Polymer Chemistry (hsv)
- Naturvetenskap (hsv)
- Kemi (hsv)
- Polymerkemi (hsv)
- Engineering and Technology (hsv)
- Chemical Engineering (hsv)
- Polymer Technologies (hsv)
- Teknik och teknologier (hsv)
- Kemiteknik (hsv)
- Polymerteknologi (hsv)
- Natural Sciences (hsv)
- Chemical Sciences (hsv)
- Materials Chemistry (hsv)
- Naturvetenskap (hsv)
- Kemi (hsv)
- Materialkemi (hsv)
Genre
- government publication (marcgt)
Indexterm och SAB-rubrik
- ZIF-8
- PIM-1
- Mixed matrix membranes
- Polymers of intrinsic microporosity
- Separation of carbon dioxide and methane
Inställningar
Hjälp
Ingår i annan publikation. Gå till titeln
Microporous and Mesoporous Materials