Effects of the injection grout Silica sol on Bentonite [Elektronisk resurs]
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Holmboe, Michael, 1978- (författare)
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Wold, Susanna (författare)
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Petterson, Torbjörn (författare)
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KTH Skolan för kemivetenskap (CHE) (utgivare)
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KTH Skolan för kemivetenskap (CHE) (utgivare)
- Publicerad: 2011
- Engelska.
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Ingår i: Physics and Chemistry of the Earth. - 1474-7065. ; 36:17/18, 1580-1589
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Sammanfattning
Ämnesord
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- Silica sol, i.e., colloidal SiO2, may be used as a low-pH injection grout for very fine fractures in the construction of deep geological repositories for radioactive waste in Sweden and in Finland. If the bentonite barrier encounters SiO2-colloid particles under conditions favorable for aggregation, there is concern that it will modify the bentonite barrier at the bentonite/bedrock interface. In this study qualitative experiments were performed with mixed dispersions of SiO2-colloids and bentonite or homo-ionic Na/Ca-montmorillonite. Samples were prepared at different colloid concentrations and treated under various conditions such as low and high ionic strength (0.3 M NaCl), as well as dehydration and redispersing. Free swelling and settling experiments were performed in order to qualitatively compare the conditions in which SiO2-colloids affect the bulk/macro properties of bentonite. In order to study specific SiO2-colloid/montmorillonite interactions and preferred type of initial aggregation, dilute dispersions of homo-ionic montmorillonite dispersions mixed with varying concentrations of SiO2-colloids were prepared and selected samples were characterized by PCS, SEM/EDS, AFM and PXRD. The results from this study show that bentonite and montmorillonite particles can be modified by SiO2-colloids when mixed in comparable amounts, due to dehydration or high ionic strength. Some indications for increased colloidal stability for the SiO2-colloid modified clay particles were also found. From the AFM investigation it was found that initial attachment of the SiO2-colloids in Na+ dominated samples seemed to occur on the edges of the montmorillonite layers. In Ca2+ dominated samples not subjected to excess NaCl, SiO2-colloid sorption onto the faces of the montmorillonite layers was also found. In all, contact between the bentonite barrier and ungelled Silica sol should preferably be avoided.
Ämnesord
- Natural Sciences (hsv)
- Chemical Sciences (hsv)
- Physical Chemistry (hsv)
- Naturvetenskap (hsv)
- Kemi (hsv)
- Fysikalisk kemi (hsv)
- TECHNOLOGY (svep)
- Chemical engineering (svep)
- Chemical process and manufacturing engineering (svep)
- Surface and colloid chemistry (svep)
- TEKNIKVETENSKAP (svep)
- Kemiteknik (svep)
- Kemisk process- och produktionsteknik (svep)
- Yt- och kolloidkemi (svep)
Indexterm och SAB-rubrik
- Bentonite
- Bentonite colloids
- Silica sol
- Silica colloids
- Colloidal stability
- Colloid interactions
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