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Sökning: onr:7hcmq6zd5lt4bl3f > Cellulose-based Nan...

  • Geng, Shiyu (författare)

Cellulose-based Nanocomposites – The Relationship between Structure and Properties [Elektronisk resurs]

  • E-bokAvhandlingEngelska2018

Förlag, utgivningsår, omfång ...

  • Publicerad:Luleå :Publicerad:Luleå University of Technology,Publicerad:2018
  • rordacarrierrdacarrier

Nummerbeteckningar

  • LIBRIS-ID:7hcmq6zd5lt4bl3f
  • ISBN:9789177901839
  • Ogiltigt nummer / annan version:9789177901822
  • http://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-70411uri
  • urn:nbn:se:ltu:diva-70411urn

Kompletterande språkuppgifter

  • Språk:engelska

Ingår i deldatabas

Serie

  • Doctoral thesis / Luleå University of Technology 1 jan 1997 → …,1402-1544

Anmärkningar

  • Härtill 5 uppsatser
  • Knut och Alice Wallenbergs Stiftelse
  • Bio4Energy
  • Diss. (sammanfattning), 2018
  • gratis
  • Nanocellulose materials extracted from various types of biomass have recently attracted significant attention. Due to their remarkable mechanical properties, large surface area and biodegradability, they can be promising reinforcements in nanocomposites. Cellulose-based nanocomposites constitutive of nanocellulose reinforcements and biodegradable polymer matrices have great potential to be used in environmentally friendly applications to replace fossil-based materials. However, the challenge of controlling their nanoscale structure, especially achieving good dispersion of nanocellulose in hydrophobic polymer matrices, still poses significant obstacles to producing high-performance nanocomposites. Therefore, this thesis reports several methods for structural modification of cellulose-based nanocomposites toward the objectives of improving the dispersion of nanocellulose and enhancing the properties of the nanocomposites. The methods include in situ emulsion polymerization in the presence of nanocellulose, crosslinking of polymer matrix, grafting of polymer brushes to nanocellulose and drawing of nanocomposites to obtain aligned structures. The resulting mechanical, thermal and other related properties are investigated, and the relationship between structure and properties of the nanocomposites are discussed. To address the challenge of achieving good dispersion of nanocellulose in hydrophobic matrices, in situ emulsion polymerization of vinyl acetate monomer in the presence of cellulose nanocrystals has been developed. Microscopy results show that the in situ method improves the compatibility between nanocellulose and hydrophobic polymers, which consequently improves the dispersion of nanocellulose in the nanocomposites. Compared with direct mixed polymer/nanocellulose composites, the in situ synthesized nanocomposites exhibit higher stiffness and strength arising from their superior interphase volume, which is confirmed theoretically and experimentally. Crosslinking of partially hydrolyzed poly(vinyl acetate) by borate additives under different pH conditions has been studied to further enhance mechanical properties of the nanocomposites. Moreover, the “grafting to” modification method also helps to overcome this challenge. It is revealed that poly(ethylene glycol)-grafted cellulose nanofibers disperse better in poly(lactic acid) matrix than unmodified cellulose nanofibers, which is attributed to the improved compatibility and steric effect provided by the covalently grafted poly(ethylene glycol) brushes. To substantially enhance the unidirectional mechanical properties of cellulose-based nanocomposites, a highly aligned structure in the materials is obtained through the drawing process. Drawing conditions including temperature, speed and draw ratio show considerable effects on the mechanical and thermal properties of the nanocomposites. Furthermore, the aligned nanocomposites consisting of poly(lactic acid) matrix and ultra-low weight fraction of poly(ethylene glycol)-grafted cellulose nanofibers demonstrate competitive strength, superb toughness and interesting optical behaviors compared with other aligned nanocellulose-based materials reported in the literature, indicating their potential to be further developed for large-scale environmentally friendly applications.

Ämnesord och genrebeteckningar

Biuppslag (personer, institutioner, konferenser, titlar ...)

  • Oksman, Kristiina,1959- (preses)
  • Matuana, Laurent (opponent)
  • Luleå tekniska universitetInstitutionen för teknikvetenskap och matematik (utgivare)

Sammanhörande titlar

  • Del av/supplement till:channel record
  • Annan version:Annat format9789177901822

Seriebiuppslag

  • Doctoral thesis / Luleå University of Technology 1 jan 1997 → …,1402-1544

Internetlänk

Länkade data-URI:er (test)

  • https://id.kb.se/marc/Thesis ()
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